Get another pan ready for "sweating" the peppers after roasting, this is an important step, deep enough to hold all the peppers you are roasting, and a cover, I'm using a lasagna pan and foil.
Broil the peppers, as close to the broiler as possible, and turn on the light, you will need to watch very closely, as they will blister up rather quickly, when one side is blackening after approximately 2 to 3 minutes, you will need to pull them out and turn them over to roast and blister the other side. I have the second pan to broil in the oven the whole time, allowing the peppers to bake a bit and soften up, you will not need to flip these, just let them stay in the oven.
This is how they will look when blackened and blistered properly. They are not burnt, they are perfection. You might get wisps of smoke coming from the oven, and some of the peppers will bloat and pop from the steam building up on the inside. If you hear popping, that is a GOOD sound!
After they are done, transfer the roasted peppers to your sweating pan, and cover, tightly isn't necessary, just enough to hold the heat and steam in. Let them steam or "sweat" for about 30 minutes.
all covered, now you can do some fun stuff with the kids till you are ready to peel the chili
When ready to peel the chili, I have found that using an ice bath is the best way. It cools off the peppers enough to handle, and keeps your hands a little cool and you unaware of the Capsaicin that is digging into your skin. If you are really sensitive, gloves can be used, and are recommended! I have to stop for a minute and say thanks to The Frontier Restaurant( http://www.frontierrestaurant.com/ ) without having worked there for almost three years, I would have never known the special step of peeling green chili. Unbeknowst to many people, most New Mexican's do not roast their own chili.... why? Well it is roasted in such an abundance, they can already purchase it roasted, peeled, and chopped. Sure we can get it that way here in Florida, but it's only in little cans. Canning does something BAD to green chili, it's NOT the same. I used to buy huge Bueno chili http://www.buenofoods.com/ frozen tubs of green chili. They did all the hard work. The Frontier Restaurant roasted their own chili, and in idle hours of the work day, employees would peel the roasted chili. There always was a chili peeling station in the back, my first day of work, I peeled chili for 8 hours!
The peels and the seeds. it seems like a lot, and really out of 10 pounds of green chili, the amount of flesh you get to actually eat is probably close to 6 or 7 pounds.
I chopped the chili and placed into bags for freezing. Chili should be frozen. Even though it is quite potent it will go bad, mold and rot, after a few weeks in the fridge. But what kind of moron lets the chili sit in the fridge for that long?
I roasted about 10 pounds of chili, and got about 7 to 8 cups of chopped green chili, I got 5 bags total, each with about 1 to 2 cups of chili
This same process can be used for any chili pepper, red peppers, green peppers, jalapenos, anything. If you want your own roasted red peppers follow the same steps, and you will get the same results with red peppers. I highly suggest this if you find a bunch of red peppers for really cheap... but that's not likely to happen. LOL, but doing it yourself is cheaper than buying roasted red peppers.